The key when removing the stain is to work gently from the outer edge of the stain inward.
Mascara
Use a spray or liquid stain remover
Lipstick
Rubbing Alcohol - Start with alcohol, which works well. Do not rub, or you'll spread the mark. Simply take a clean, white cloth and moisten it with alcohol. Then, blot the lipstick stain, which will disappear.
Liquid Dishwashing - Detergent Another home remedy is to use a mild liquid dishwashing detergent such as Dawn, formulated to fight grease. For this method of lipstick stain removal, dab on a little Dawn, let it set for about 10 minutes, then gently begin working on the stain from the outside edges inward. You could use laundry detergent, shampoo, or other similar type of cleanser as long as it does not contain any lighteners, brighteners, or bleach.
Ammonia - Another great home remedy for removing lipstick stains is ammonia. Again, start by blotting off as much of the stain as you can, using plain water. When done, use a cotton swab moistened with ammonia to dab at the stain. Once the stain begins to fade, wash the shirt by hand in warm soapy water.
Foundation make-up
Wipe off the excess, then soak in ammonia solution (1 tsp ammonia to 2 cups of cold water). Launder as usual.